A COMOSITE ELECTRODE FOR STUDYING POWDERED ELECTROACTIVE MATERIALS - PREPARATION AND PERFORMANCE

被引：15

作者：

KEDDAM, M ^{[1
]}

SENYARICH, S ^{[1
]}

TAKENOUTI, H ^{[1
]}

BERNARD, P ^{[1
]}

机构：

[1] AAR,SAFT,F-91460 MARCOUSSIS,FRANCE

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1994年 / 24卷 / 10期

关键词：

D O I：

10.1007/BF00241196

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An advance in Ni-Cd rechargeable battery technology is being achieved by introducing positive active material made of pasted nickel hydroxide spherical particles (SP) into a nickel foam. The performance of this kind of electrode, and particularly its improved volumic capacity, are determined by several technological factors, the contributions of which are difficult to dissociate. A composite electrode was prepared by electrodeposition of nickel from a Ni(OH)2 particle suspension in a Watts' bath. A single layer of particles was partly embedded in the nickel coating grown on a nickel support. It is shown that the contribution of the metallic nickel matrix is negligibly small in both kinetic and spectroscopic responses of the electrode hence allowing the behaviour of the nickel hydroxide particles to be investigated.

引用

页码：1037 / 1043

页数：7

共 8 条

[1]

BABJAK J, 1993, FAL EL SOC M NEW ORL, V2, P100

[2]

BERNARD P, 1992, THESIS U PARIS 6

[3] OXIDATION AND REDUCTION OF NICKEL HYDROXIDE AT CONSTANT POTENTIAL [J].