RHODIUM(III)-PROMOTED BINUCLEAR C-H ACTIVATION OF PI-COMPLEXED ETHYLENE AND PHENYLACETYLENE AND THE FORMATION OF HYDRIDE-BRIDGED RH-PT HETEROBIMETALLIC COMPLEXES

被引：12

作者：

STANG, PJ

CAO, D

机构：

[1] Department of Chemistry, The University of Utah, Salt Lake City

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of (eta5-C5Me5)Rh(PMe3)(OTf)2 with (pi-C2H4)Pt(PPh3)2 and (pi-PhC=CH)Pt(PPh3)2 at 25-degrees-C in CH2Cl2 results in [(eta5-C5Me5)(PMe3)Rh(mu-H)-(mu-eta2:eta1-CH=CH2)Pt(PPh3)2]2+.2OTf- and [(eta5-C5-Me5) (PMe3)Rh [mu - eta2:eta1 Ph C=C)Pt (PPh3)2]2+. 2OTf- in 72% and 76% isolated yields, respectively, as air-stable crystals.

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页码：996 / 997

页数：2

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