A RHI-CENTERED CAGE COMPOUND WITH SELECTIVE CATALYTIC PROPERTIES

被引：57

作者：

COOLEN, HKAC

VANLEEUWEN, PWNM

NOLTE, RJM

机构：

[1] CATHOLIC UNIV NIJMEGEN,NIJMEGEN SON RES CTR,TOERNOOIVELD,6525 ED NIJMEGEN,NETHERLANDS

[2] KONINKLIJKE SHELL EXPTL PROD LAB,AMSTERDAM,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 07期

关键词：

D O I：

10.1002/anie.199209051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A concave structure to bind substrates as well as two phosphite sites to bind Rh(I) are found in compound 1. The schematic drawing 2 shows the structure of the Rh(I) cage compound with a bound 4-allylcatechol molecule, which is either isomerized to methylstyrene or hydrogenated to the propyl derivative.

引用

页码：905 / 907

页数：3

共 24 条

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