CHIRAL DISCRIMINATION OF MONOSACCHARIDES THROUGH GEL FORMATION

被引:91
作者
JAMES, TD [1 ]
MURATA, K [1 ]
HARADA, T [1 ]
UEDA, K [1 ]
SHINKAI, S [1 ]
机构
[1] RES DEV CORP JAPAN, ERATO, CHEMIRECOGNICS PROJECT, KURUME, FUKUOKA 830, JAPAN
关键词
D O I
10.1246/cl.1994.273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cholesteryl phenylboronic acid (1) and its complexes with mono saccharides (2:1; 1/monosaccharide) were prepared. Many of the isolated complexes form gels in a variety of solvents, some of which display D vs L chiral discrimination. This is the first example of chiral discrimination in a saccharide based gel system.
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页码:273 / 276
页数:4
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