RADICAL CYCLIZATION OF BROMOMETHYLDIMETHYLSILYL PROPYNYL ETHERS - SERIAL RADICAL CYCLIZATIONS LEADING TO A HYDRINDENE FRAMEWORK FROM AN ACYCLIC SUBSTRATE, STEREOSELECTIVELY

被引：9

作者：

JOURNET, M ^{[1
]}

LACOTE, E ^{[1
]}

MALACRIA, M ^{[1
]}

机构：

[1] UNIV P & M CURIE,CNRS,CHIM ORGAN SYNTH LAB,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Bromomethyldimethylsiloxy-2,8,8-trimethyldec-1-en-5,9-diyne 11 is prepared and its radical cyclisation leads to a stereoselective synthesis of a hydrindene framework 13 via three consecutive 5-exo-dig, 5-exo-trigand 6-exo-digradical processes.

引用

页码：461 / 462

页数：2

共 12 条

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