DIRECT PROOF OF THE MOLECULAR-STRUCTURE OF DIMERIC TITANOCENE - THE X-RAY STRUCTURE OF MU-(ETA-5-ETA-5-FULVALENE)-DI-(MU-HYDRIDO)-BIS(ETA-5-CYCLOPENTADIENYLTITANIUM)BULLET-1.5BENZENE

被引：48

作者：

TROYANOV, SI ^{[1
]}

ANTROPIUSOVA, H ^{[1
]}

MACH, K ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CS-18223 PRAGUE 8,CZECHOSLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83204-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric titanocene crystallizes as a benzene solvate with molar ratio 1:1.5. The crystals are monoclinic, space group P2(1)/n with Z = 4 and lattice parameters a = 5.978(4), b = 14.541(6), c = 26.963(8) angstrom and beta = 92.11(2)-degrees. In the series of (C10H8)[(C5H5)TiX]2 complexes, where X = H, H/Cl (1:1), Cl or OH, the dihydrido complex has the shortest Ti-Ti distance (2.989 angstrom) and largest dihedral angle between the planes of C5H4 rings of the fulvalene ligand (17.7-degrees).

引用

页码：49 / 55

页数：7

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