INFRARED REFLECTION-ABSORPTION SPECTROSCOPY AND STM STUDIES OF MODEL SILICA-SUPPORTED COPPER-CATALYSTS

被引:74
作者
XU, XP
VESECKY, SM
GOODMAN, DW
机构
[1] Department of Chemistry, Texas A and M University, College Station
关键词
D O I
10.1126/science.258.5083.788
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The structure of model silica-supported copper catalysts has been investigated with scanning tunneling microscopy (STM) and infrared reflection-absorption spectroscopy (IRAS). The IRAS studies of CO on the model silica-supported copper catalysts indicate that there are several types of copper clusters with surface structures similar to (111), (110), and other high-index planes of single-crystal copper. The STM studies show several types of copper clusters on silica and reveal images of metal clusters on an amorphous oxide support with atomic resolution.
引用
收藏
页码:788 / 790
页数:3
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