RUTHENIUM(II) COMPLEXES OF A NEW TETRAPYRAZOLIC MACROCYCLE

被引:18
作者
MARY, F [1 ]
MARZIN, C [1 ]
SALHI, S [1 ]
TARRAGO, G [1 ]
机构
[1] UNIV MONTPELLIER 2, URA 330, F-34095 MONTPELLIER 5, FRANCE
关键词
MACROCYCLE; RU(II) COMPLEXES; H-1 AND C-13 NMR;
D O I
10.1080/10610279308029839
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new macrocycle L containing two bipyrazole subunits gives with Ru(DMSO)4Cl2 a stable trans complex in which the nature of the axial ligands has been established from H-1 and C-13 NMR, IR and UV experiments; the structure of the complexes obtained after axial ligand exchange has been mainly deduced from H-1 NMR data: a dynamic phenomenon has been observed in the case of pyridine axial ligands.
引用
收藏
页码:57 / 61
页数:5
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