POLY(N-ACYLETHYLENIMINE) COPOLYMERS CONTAINING PENDANT PENTAMETHYLDISILOXANYL GROUPS .1. SYNTHESIS

被引：24

作者：

CAI, GF ^{[1
]}

LITT, MH ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1992年 / 30卷 / 04期

关键词：

COPOLYMERS; OXAZOLINES; POLY(NORMAL-ACYLETHYLENEIMINES); POLYDISPERSITY; SILOXANE;

D O I：

10.1002/pola.1992.080300417

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

10-(Pentamethyl disiloxanyl) decyl oxzoline (Si) was synthesized. It was copolymerized with either undecyl (U) or nonyl (N) oxazolines using methyl 4-nitrobenzenesulfonate as initiator. Two series of random poly (N-acylethylenimine) copolymers, U/Si and N/Si were synthesized over the whole composition range of Si monomer with a total degree of polymerization of about 100. Narrow molecular weight distributions were obtained. At a monomer to initiator ratio of about 1060, the final degree of polymerization was 374 with a polydispersity index of 1.93. This shows the effect of chain transfer in this system.

引用

页码：649 / 657

页数：9

共 17 条

[1]

BASSIRI TG, 1967, POLYM LETT, V5, P871

[2]

CAI G, 1992, J POLYM SCI A, V32, P661

[3]

CAI G, 1982, J POLYM SCI A, V32, P673

[4] PREPARATION AND CHARACTERIZATION OF PHENYL AND UNDECYL OXAZOLINE BLOCK COPOLYMERS [J].

CAI, GF ;

LITT, MH .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (11) :3603-3618

[5]

CAI GF, 1989, CONTEMP TOP POLYM S, V6, P139

[6] SURFACE-PROPERTIES AND ABHESION OF UNDECYL OXAZOLINE BLOCK AND HOMOPOLYMERS [J].

CAI, GF ;

LITT, MH ;

KRIEGER, IM .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1991, 29 (07) :773-784

[7]

DREME M, 1984, TETRAHEDRON, V4, P349

[8] POLY(N-ACYLETHYLENIMINES) WITH PENDANT CARBAZOLE DERIVATIVES .1. SYNTHESIS [J].

HSIEH, BR ;

LITT, MH .

MACROMOLECULES, 1985, 18 (07) :1388-1394

[9]

KAISER M, 1980, Patent No. 4203900

[10] POLYMERIZATION OF CYCLIC IMINO ETHERS .10. KINETICS, CHAIN TRANSFER, AND REPOLYMERIZATION [J].

LITT, M ;

LEVY, A ;

HERZ, J .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (05) :703-727

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