N-(3,4-DIHYDRO-4-OXOQUINAZOLIN-3-YL)PYRIDINIUM IMIDES - AZIRIDINATING AGENTS FOR ALKENES - MEASUREMENT OF ROTATIONAL BARRIERS AROUND EACH N-N BOND IN AN N-N-N SYSTEM

被引：2

作者：

ATKINSON, RS ^{[1
]}

BARKER, E ^{[1
]}

EDWARDS, PJ ^{[1
]}

THOMSON, GA ^{[1
]}

机构：

[1] ZENECA SPECIALTIES, MANCHESTER M9 8ZS, LANCS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 07期

关键词：

D O I：

10.1039/c39950000727

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridinium imides 3-5 and 8 are obtained as crystalline solids from the reaction of 3-acetoxyaminoquinazolinones 2 and 10 with the corresponding pyridines; barriers to rotation around each of the N-N bonds in 3 have been measured by NMR spectroscopy, and the imides 3-5 react both with styrene and with diethyl fumarate to give the corresponding aziridines.

引用

页码：727 / 728

页数：2