CHLORINATION OF UNSYMMETRICAL SULFIDES

被引：104

作者：

TULEEN, DL

STEPHENS, TB

机构：

[1] Department of Chemistry, Vanderbilt University, Nashville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chlorination of unsymmetrical aliphatic sulfides by N-chlorosuccinimide (NCS) in carbon tetrachloride has been investigated. The resulting mixtures of α-chloro sulfides have beenanalyzedusing nmr spectrometry. The reaction of benzyl t-butyl sulfide and benzyl p-methoxybenzyl sulfide with sulfuryl chloride results in carbonsulfur bond cleavage; reaction of these substrates with NCS affords α-chloro sulfides. Ratios of chlorinated products from the reactions of ethyl methylsulfide with NCS and sulfuryl chloride also indicate significant differences between these chlorinating agents. © 1969, American Chemical Society. All rights reserved.

引用

页码：31 / &