CHARACTERIZATION OF THE 1ST MIXED-VALENT LIQUID-CRYSTALLINE MATERIALS - SYNTHESIS AND STRUCTURAL-PROPERTIES OF NEW BINUCLEAR RUTHENIUM CARBOXYLATES

被引：20

作者：

CUKIERNIK, FD

MALDIVI, P

GIROUDGODQUIN, AM

MARCHON, JC

IBNELHAJ, M

GUILLON, D

SKOULIOS, A

机构：

[1] CTR ETUD NUCL GRENOBLE,DEPT RECH FUNDAMENTALE,CHIM COORDINAT LAB,CNRS,URA 1194,85X,F-38041 GRENOBLE,FRANCE

[2] INST CHARLES SADRON,INST PHYS & CHIM MAT STRASBOURG,MAT ORGAN GRP,F-67083 STRASBOURG,FRANCE

来源：

LIQUID CRYSTALS | 1991年 / 9卷 / 06期

关键词：

D O I：

10.1080/02678299108055013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses and structural properties of new binuclear ruthenium complexes with long chain carboxylates, of general formula Ru2(RCO2)4X (R = C8H17, C11H23 and X = Cl, RCOO), are reported. The thermodynamic behaviour of these compounds is strongly influenced by the nature of the counterion X. The chloro complexes (X = Cl) are not mesomorphic whereas the carboxylato species (X = RCOO) are shown to exhibit a thermotropic columnar mesophase, thus providing the first example of a mixed-valent liquid-crystalline material.

引用

页码：903 / 906

页数：4

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