MECHANICAL-STRESS AND REACTIVITY IN ORGANIC-SOLIDS

被引：111

作者：

MCBRIDE, JM

SEGMULLER, BE

HOLLINGSWORTH, MD

MILLS, DE

WEBER, BA

机构：

[1] CELANESE SPECIALTY OPERAT,CORPUS CHRISTI,TX 78469

[2] UNIV CAMBRIDGE,PHYS CHEM,CAMBRIDGE CB2 1EP,ENGLAND

[3] TENNESSEE EASTMAN CO,KINGSPORT,TN 37662

[4] LEHIGH UNIV,CHEM,BETHLEHEM,PA 18015

来源：

SCIENCE | 1986年 / 234卷 / 4778期

关键词：

ORGANIC COMPOUNDS - Chemical Reactions - SOLIDS;

D O I：

10.1126/science.234.4778.830

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Organic single crystals provide an ideal model for studying the factors that influence chemical processes in structured media. Reaction trajectories are well defined and reveal the influence of spontaneous mechanical stresses equivalent to tens of thousands of atmospheres. Analysis of molecular and crystal structures helps to explain both local mechanical properties, which influence reactions, and bulk properties such as melting point, compressibility, and surface energy.

引用

页码：830 / 835

页数：6

共 50 条

[1]

ADAMSON AW, 1982, PHYSICAL CHEM SURFAC, pCH7

[2] BRILLOUIN-SCATTERING IN SINGLE-CRYSTALS OF PLASTIC CYCLOHEXANE [J].