COMPLEXES OF TERTIARY PHOSPHINES WITH IRON(II) AND DINITROGEN, DIHYDROGEN, AND OTHER SMALL MOLECULES

被引：64

作者：

HILLS, A ^{[1
]}

HUGHES, DL ^{[1
]}

JIMENEZTENORIO, M ^{[1
]}

LEIGH, GJ ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,INST PLANT SCI RES,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 391卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85070-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of [FeCl2(diphosphine)2] with sodium borohydride in ethanol produces the hydrides [FeH3(diphosphine)2]+ in high yield. These complexes react with a variety of small molecules including N2 to give further complexes. CO2 and CS2 insert into the iron hydride bond to yield formato- and dithioformato-complexes, respectively, and carboxymethyl acetylene and phenyl acetylene yield a cyclic alkenyl complex and an acetylide, respectively. © 1990.

引用

页码：C41 / C44

页数：4

共 7 条

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