COMPLEXES OF TERTIARY PHOSPHINES WITH IRON(II) AND DINITROGEN, DIHYDROGEN, AND OTHER SMALL MOLECULES

被引:64
作者
HILLS, A [1 ]
HUGHES, DL [1 ]
JIMENEZTENORIO, M [1 ]
LEIGH, GJ [1 ]
机构
[1] UNIV SUSSEX,AFRC,INST PLANT SCI RES,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND
关键词
D O I
10.1016/0022-328X(90)85070-F
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The treatment of [FeCl2(diphosphine)2] with sodium borohydride in ethanol produces the hydrides [FeH3(diphosphine)2]+ in high yield. These complexes react with a variety of small molecules including N2 to give further complexes. CO2 and CS2 insert into the iron hydride bond to yield formato- and dithioformato-complexes, respectively, and carboxymethyl acetylene and phenyl acetylene yield a cyclic alkenyl complex and an acetylide, respectively. © 1990.
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页码:C41 / C44
页数:4
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