SELF-RECOGNITION BY THE IRON CHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] IN THE FORMATION OF (RR,SS)-[(ETA-5-C5H5)FE(CO)(PPH3)COCH2]2CH2

被引：13

作者：

BODWELL, GJ ^{[1
]}

DAVIES, SG ^{[1
]}

PRESTON, SC ^{[1
]}

机构：

[1] DYSON PERRINS LAB,S PARKS RD,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86259-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complete self-recognition of chirality is observed in the Michael addition of the enolate derived from R,S-[(eta-5-C5H5)Fe(CO)(PPh3)-COCH3] to the acryloyl complex R,S-[(eta-5-C5H5)Fe(CO)(PPh3)-COCH = CH2)] to generate exclusively the single diastereoisomer of the glutaroyl complex RR,SS-[(eta-5-C5H5)Fe(CO)(PPh3)COCH2]2CH2.

引用

页码：C56 / C58

页数：3

共 5 条

[1] IMPROVED STEREOCHEMICAL CONTROL AND MECHANISTIC ASPECTS OF THE ALKYLATION OF ENOLATES DERIVED FROM [(N5-C5H5)FE(CO)(PPH3)COCH2R]
BROWN, SL
DAVIES, SG
FOSTER, DF
SEEMAN, JI
WARNER, P
[J]. TETRAHEDRON LETTERS, 1986, 27 (05) : 623 - 626
[2] DAVIES SG, 1987, B SOC CHIM FR, P608
[3] THE ASYMMETRIC-SYNTHESIS OF BETA-LACTAMS - STEREOCONTROLLED ASYMMETRIC TANDEM MICHAEL ADDITIONS AND SUBSEQUENT ALKYLATIONS OF E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH=CHME] - X-RAY CRYSTAL-STRUCTURE OF (RS)-E-[(ETA-5-C5H5)FE(CO)(PPH3)COCH - CHME]
DAVIES, SG
DORDORHEDGECOCK, IM
SUTTON, KH
WALKER, JC
JONES, RH
PROUT, K
[J]. TETRAHEDRON, 1986, 42 (18) : 5123 - 5137
[4] DAVIES SG, 1990, ALDRICHIM ACTA, V23, P31
[5] MOWSS JR, 1989, J ORGANOMET CHEM, V363, P351

← 1 →