OXIDATIVE TRANSFORMATION OF FUNCTIONALIZED METHYL KETONES INTO ALPHA-KETOCARBOXYLIC ESTERS

被引：5

作者：

BOEYKENS, M ^{[1
]}

DEKIMPE, N ^{[1
]}

机构：

[1] STATE UNIV GHENT,FAC AGR SCI,ORGAN CHEM LAB,COUPURE LINKS 653,B-9000 GHENT,BELGIUM

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 22期

关键词：

D O I：

10.1080/00397919208021144

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl ketones are oxidatively transformed into alpha-keto esters by metal ion assisted alcoholysis of the corresponding beta-keto-alpha,alpha-dichloroalkyl sulfides.

引用

页码：3285 / 3289

页数：5

共 3 条

[1] SYNTHESIS AND PROPERTIES OF THE ALPHA-KETO ACIDS [J].

COOPER, AJ ;

GINOS, JZ ;

MEISTER, A .

CHEMICAL REVIEWS, 1983, 83 (03) :321-358

[2] DIHALOGENATION OF BETA-KETO SULFIDES - SYNTHESIS OF ALPHA-KETO METHYL-ESTERS AND ALPHA-KETO S-PHENYL THIOESTERS [J].

FORTES, CC ;

SOUTO, CRO ;

OKINO, EA .

SYNTHETIC COMMUNICATIONS, 1991, 21 (20) :2045-2052

[3] PREPARATION OF ALPHA,ALPHA-DIALKYL-BETA-HALOKETONES [J].

SULMON, P ;

DEKIMPE, N ;

SCHAMP, N .

ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1989, 21 (01) :91-104

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