REVERSIBLE REDOX SYSTEMS R6SN2/R3SN+ ON PLATINIZED PLATINUM ELECTRODE

被引：10

作者：

DORETTI, L

TAGLIAVI.G

机构：

[1] Instituto di Chimica Analitica, Universitá di Padova

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)90914-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reversibility has been found for organometallic redox couples R6Sn2/R3Sn+. Formal standard potentials Eo at a platinized platinum electrode have been determined for the systems having R = Me, Et, Bu and Ph in methanol and in methanol/benzene. The presence of R3Sn radicals at the platinized platinum electrode-solution interface seems to be responsible for the reversibility. The Eo values obtained under different conditions, are discussed. © 1968.

引用

页码：203 / &

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