LIGNINS RELEASED FROM PICEA-ABIES SUSPENSION-CULTURES - TRUE NATIVE SPRUCE LIGNINS

被引:29
作者
BRUNOW, G [1 ]
EDE, RM [1 ]
SIMOLA, LK [1 ]
LEMMETYINEN, J [1 ]
机构
[1] UNIV HELSINKI,DEPT BOT,SF-00170 HELSINKI 17,FINLAND
关键词
cell cultures; lignins; molecular weight distribution; NMR spectra; Picea abies; Pinaceae; spruce;
D O I
10.1016/0031-9422(90)85183-G
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Suspension-cultured cells of Picea abies release lignin in the nutrient medium. Chemical analyses, 1H and 13C NMR spectroscopy of this material show that they represent carbohydrate-free guaiacyl type lignins with a high proportion of cinnamyl alcohol side chains a somewhat lower methoxyl content than milled wood lignin from spruce. The molecular weight distribution determined by HPSEC gave a weight average Mr of 14 200 and a number average weight close to 4000. These are the first conifer lignin samples to be characterized without chemical or mechanical degradation. © 1990.
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页码:2535 / 2538
页数:4
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