SYNTHESIS, CIRCULAR-DICHROISM AND ABSOLUTE STEREOCHEMISTRY OF CHIRAL SPIROAROMATIC COMPOUNDS - 9,9'-SPIROBIFLUORENE DERIVATIVES

被引：25

作者：

HARADA, N

ONO, H

NISHIWAKI, T

UDA, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral spiroaromatic compounds (+)-2 and (+)-3 with 9,9'-spirobifluorene skeletons have been synthesized and their absolute stereostructures have been unambiguously determined to be R, by application of the CD exciton chirality method; the R absolute stereochemistry of (-)-[6,6]-vespirene 1 was established by chemical correlation with these compounds.

引用

页码：1753 / 1755

页数：3

共 7 条

[1] CHRIROPTICAL PROPERTIES AND ABSOLUTE CONFIGURATION OF 9,9'-SPIROBIFLUORENE DERIVATIVES [J].