THE CRYSTAL-STRUCTURE OF [6-NITRO-12,14-DIMETHYL-3,9-BIS(PROPYLSULPHONYL)-1,2,4,8,10,11-HEXAAZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2-)-N-1, N-4, N-8, N-11]NICKEL(II) AND [12,14-DIMETHYL-3,9-BIS(ETHYLSULPHONYL)-1,2,4,8,10,11-HEXAAZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2)-N-1, N-4, N-8, N-11]NICKEL(II)

被引:11
作者
DVORKIN, A
BOUROSH, P
SIMONOV, Y
ARION, V
GRADINARU, J
GERBELEU, N
机构
[1] MOLDAVIAN ACAD SCI,INST APPL PHYS,KISHINEV 277028,MOLDOVA
[2] MOLDAVIAN ACAD SCI,INST CHEM,KISHINEV 277028,MOLDOVA
关键词
D O I
10.1016/0277-5387(94)00284-L
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hexaazamocrocyclic complexes [6-nitro-12,14-dimethyl-3,9-bis(sulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]nickel(II) and [12,14-dimethyl-3,9-bis(ethylsulphonyl)-1,2,4,8,10,11-hexaazacyclotetra-deca-2,4,6,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]nickel(II) have been synthesized by a template procedure starting from an open-chain precursor. The crystal structure of both macrocycle products showed a square planar coordination geometry with cis-positioned-SR groups relative to the nickel atom.
引用
收藏
页码:571 / 577
页数:7
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