METAL-PTERIDINE COMPLEXES HAVING 3-DIMENSIONAL HYDROGEN-BONDED NETWORKS

被引：55

作者：

MITSUMI, M

TOYODA, J

NAKASUJI, K

机构：

[1] GRAD UNIV ADV STUDIES,DEPT FUNCT MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

[2] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

[3] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 12期

关键词：

D O I：

10.1021/ic00116a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three-dimensional hydrogen-bonded (H-bonded) networks of metal-pteridine complexes are realized as the first examples which contain the following three intermolecular interactions: (1) H-bonding between coordinated water molecules and pteridine ligands; (2) a stacking interaction between the pteridine ligands; (3) H-bonding between the pteridine ligands. In this work, we selected lumazine (HLM) and pterin (HPR) as ligands and prepared the copper(II) and zinc(II) complexes [Cu(LM)(2)(H2O)(2)] (1), [Cu(PR)(2)(H2O)(2)] (2), and [Zn(PR)(2)(H2O)(2)].2H(2)O (3).

引用

页码：3367 / 3370

页数：4

共 17 条

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