STRAINED PERYLENES BY CLAMPING - THE CORONENE ISOMER DICYCLOPENTA[1,2,3-CD-1',2',3'-LM]PERYLENE AND DIMETHANOPERYLENE

被引：16

作者：

JAWOREK, W ^{[1
]}

VOGTLE, F ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,GERHARD DOMAGK STR 1,W-5300 BONN 1,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 02期

关键词：

AROMATICITY; METHANONAPHTHALENE; PERYLENES; POLYCYCLES; STRAINED HYDROCARBONS;

D O I：

10.1002/cber.19911240216

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perylene (3) is clamped by C2 and C1 bridges with formation of the heptacyclic title compound dicyclopenta[1,2,3-cd:1',2',3'-lm]perylene (10) (characterized) and 1H,6H-dicyclobuta[1,2,3-cd:1',2',3'-lm]perylene (4) (detected by mass spectrometry and H-1-NMR absorptions). The influence of strain on UV and fluorescence spectra and on cyclic voltammetry is discussed.

引用

页码：347 / 352

页数：6

共 37 条

[1] ELECTRICAL CONDUCTIVITY OF THE PERYLENE-BROMINE COMPLEX
AKAMATU, H
INOKUCHI, H
MATSUNAGA, Y
[J]. NATURE, 1954, 173 (4395) : 168 - 169
[2] AVOYAN RL, 1963, J STRUCT CHEM, V41, P581
[3] 1H-CYCLOBUTA[DE]NAPHTHALENE (1,8-METHANONAPHTHALENE)
BAILEY, RJ
SHECHTER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (26) : 8116 - 8117
[4] BAILEY RJ, 1974, THESIS OHIO STATE U
[5] Concerning perylene-tribromide - A response to the comments of A Zinke and A Pongratz
Brass, K
Clar, E
[J]. BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1936, 69 : 1977 - 1979
[6] Perylen tri-halogenide. Summary by A. Zinke and A. Pongratz.
Brass, K
Clar, E
[J]. BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1939, 72 : 604 - 607
[7] BRASS K, 1932, BER DTSCH CHEM GES, V5, P1660
[8] BUUHOI NP, 1956, RECL TRAV CHIM PAY B, V75, P1194
[9] CARD P, 1976, THESIS OHIO STATE U
[10] SYNTHESIS AND CHEMISTRY OF 1H-CYCLOBUTA[DE]NAPHTHALENES, 1-ALKYLIDENE-1H-CYCLOBUTA[DE]NAPHTHALENES, AND 1H-CYCLOBUTA[DE]NAPHTHALEN-1-ONE
CARD, PJ
FRIEDLI, FE
SHECHTER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (19) : 6104 - 6114

← 1 2 3 4 →