THE INFLUENCE OF CATALYST-SUPPORTING METHODS ON ELECTROCHEMICAL ACTIVITY AND THE RESULTANT STABILITY OF AIR ELECTRODES ACTIVATED WITH IRON PHTHALOCYANINE

被引:11
作者
HIRAI, T
YAMAKI, JI
YAMAJI, A
机构
[1] NTT, Ibaraki Electrical, Communication Lab, Tokai, Jpn, NTT, Ibaraki Electrical Communication Lab, Tokai, Jpn
关键词
AIR ELECTRODES - CARBON SUPPORTS - HYDROGEN PEROXIDE DECOMPOSITION RATE - POLARIZATION CURVES;
D O I
10.1007/BF00615997
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
To improve the performance of air electrodes, the dependence of iron phthalocyanine (FePc) catalytic effects on preparation methods was examined. The methods used were mixture (Electrode 1), impregnation (Electrode 2) and direct synthesis (Electrode 3). Electrodes 2 and 3 showed higher potentials during cathodic polarization up to 10 mA cm** minus **2 than Electrode 1. The rate of chemical destruction of H//2O//2 decreased in the order Electrodes 3 greater than Electrode 2 greater than Electrode 1. Electrode 3 showed the smallest potential drop for a discharge at 10 mA cm** minus **2, 0. 09 V after 50 h. However, the potential of Electrode 2 decreased with discharge, becoming 0. 09 V lower than that of Electrode 3 after a 50 h discharge at 10 mA cm** minus **2. Once the potential drop occurred, the potential was not recovered by resting or by drying the electrode.
引用
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页码:441 / 445
页数:5
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