ALLYL, BENZYL AND PROPARGYL SILANES VIA THE SUZUKI REACTION

被引：21

作者：

SODERQUIST, JA

SANTIAGO, B

RIVERA, I

机构：

[1] Department of Chemistry, University of Puerto Rico Rio Piedras, Puerto, Rico

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)97783-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The clean, efficient Pd-catalyzed cross-coupling of vinyl, alkynyl and aryl bromides with the air-stable organoborane, 10-trimethylsilylmethyl-9-oxa-10-borabicyclo[3.3.2]decane (2) gives excellent yields of the corresponding silylmethylated products, proceeding with complete retention of configuration in the first case. © 1990.

引用

页码：4981 / 4984

页数：4

共 35 条

[1]

Armitage D. A., 1982, COMPREHENSIVE ORGANO, V2, P1

[2] REACTIONS OF ORGANIC HALIDES WITH R3MMR3 COMPOUNDS (M=SI,GE,SN) IN PRESENCE OF TETRAKIS(TRIARYLPHOSPHINE) PALLADIUM [J].