METHYL TORSION IN C2H4-N(CH3)N, N =1 OR 2

被引：13

作者：

ENGELN, R

REUSS, J

机构：

[1] University of Nijmegen, 6525 ED Nijmegen, Toernooiveld

来源：

CHEMICAL PHYSICS | 1991年 / 156卷 / 02期

关键词：

D O I：

10.1016/0301-0104(91)80090-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Torsional Raman spectra of trans-2-butene, cis-2-butene, 2-methylpropene and propene are recorded. the molecular parameters describing the torsional motions are determined. Especially, the torsional barrier parameters, V3, and the reduced moments of inertia, F, of the tops are compared with the values determined from MW data. We conclude that one has to analyse together MW and Raman data in order to obtain a reliable description of internal motions.

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页码：215 / 222

页数：8

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