DEUTERIUM NUCLEAR-MAGNETIC-RESONANCE CHARACTERIZATION OF SUPPORTED RHODIUM CATALYSTS - EFFECT OF THE SUPPORT

被引：16

作者：

CHANG, TH ^{[1
]}

CHENG, CP ^{[1
]}

YEH, CT ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 11期

关键词：

D O I：

10.1021/j100190a009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-support interactions were investigated by H-2 NMR for deuterium adsorbed on Rh supported on SiO2, Al2O3, TiO2 (in a non-SMSI state), NaY zeolite, and MgO. Two types of adsorbed species, Dm and Dw, with distinct chemical shifts irrespective of supports, were detected on all supports except that Dw was not detected on Rh/Al2O3. The molar fractions also support dependent. These results indicate that the major effects of the support are the number of active sites and the motions of Dm and Dw.

引用

页码：4151 / 4154

页数：4

共 33 条

[1] INFRARED STUDY OF NITRIC-OXIDE ADSORBED ON RHODIUM-ALUMINA CATALYST
ARAI, H
TOMINAGA, H
[J]. JOURNAL OF CATALYSIS, 1976, 43 (1-3) : 131 - 142
[2] ARKAWA H, 1984, CHEM LETT, P1607
[3] PT-195 NMR-STUDY OF PT/TIO2 AND PT/SIO2 CATALYSTS - STRONG METAL SUPPORT INTERACTION
BUCHER, JP
VANDERKLINK, JJ
GRAETZEL, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (04) : 1209 - 1211
[4] A SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE STUDY OF DEUTERIUM ADSORBED ON RHODIUM SILICA - EXCHANGE BETWEEN MOBILE AND WEAKLY ADSORBED DEUTERIUM
CHANG, TH
CHENG, CP
YEH, CT
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) : 5239 - 5244
[5] CORRELATION OF O-17 NMR AND O-17 NQR DATA FOR SOME AROMATIC CARBONYL-COMPOUNDS
CHENG, CP
LIN, SC
SHAW, GS
[J]. JOURNAL OF MAGNETIC RESONANCE, 1986, 69 (01) : 58 - 67
[6] MAGNETIC-RESONANCE STUDIES OF HYDROGEN-REDUCED RH/TIO2 CATALYSTS
CONESA, JC
MALET, P
MUNUERA, G
SANZ, J
SORIA, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (14) : 2986 - 2992
[7] C-13 NMR OF CO CHEMISORBED ON RH DISPERSED ON AL2O3
DUNCAN, TM
YATES, JT
VAUGHAN, RW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (07) : 3129 - 3130
[8] A C-13 NMR-STUDY OF THE ADSORBED STATES OF CO ON RH DISPERSED ON AL2O3
DUNCAN, TM
YATES, JT
VAUGHAN, RW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (02) : 975 - 985
[9] ADSORBED STATES OF CO ON DISPERSED METALS - QUANTITATIVE-ANALYSIS WITH C-13 NMR-SPECTROSCOPY
DUNCAN, TM
ROOT, TW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (15) : 4426 - 4432
[10] GARLAND CW, 1965, J PHYS CHEM-US, V169, P1188

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