POLYOL METAL-COMPLEXES .10. LEAD(II) MESO-OXOLANE-3,4-DIOLATE(2-) MONOHYDRATE - A POLYMERIC LEAD ALKOXIDE FROM AQUEOUS-SOLUTION

被引：4

作者：

KLUFERS, P

SCHUHMACHER, J

机构：

[1] Institut Für Anorganische Chemie, Universität Engesserstraße, Karlsruhe, 76128

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 01期

关键词：

LEAD; MESO-OXOLANE-3,4-DIOLATE(2-); ANHYDROERYTHRITOL; COORDINATION POLYMER; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19956210106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the colourless crystals of Pb(C4H6O3) (.) H2O (P2(1)/c, a = 569.8(3), b = 607.6(4), c = 1856.9(9)pm, beta = 89.90(4)degrees, V = 642.9(6) (.) 10(6) pm(3), Z = 4), lead(II)- and meso-oxolane-3,4-diolate(2-) ions form a one-dimensional coordination polymer; Pb-II is coordinated with four bridging alkoxide O-atoms (mean distance: 234.5 pm); some 100 pm more distant two mu-O-atoms of water molecules coordinate the lead ion.

引用

页码：19 / 22

页数：4

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