SURFACE-PROPERTIES AND CATALYTIC BEHAVIOR IN THIOPHENE HYDRODESULFURIZATION ON MO-MODIFIED AND NIMO-MODIFIED HZSM-5 ZEOLITES

被引：2

作者：

SPOJAKINA, AA

KOSTOVA, NG

机构：

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1992年 / 57卷 / 12期

关键词：

D O I：

10.1135/cccc19922509

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zeolite HZSM-5 containing 1 wt.% Ni and 10 wt.% Mo has been investigated using IR spectroscopy and thiophene hydrodesulfurization (HDS). The IR spectra indicate the strong interaction of molybdenum and nickel with zeolite lattice, forming polymolybdates of different composition. The acidity of the samples is influenced by the composition and reduction treatment. The zeolite is found to exhibit shape selectivity during thiophene conversion.

引用

页码：2509 / 2514

页数：6

共 20 条

[1] SURFACE-PROPERTIES OF MOLYBDENUM-IMPREGNATED ZSM-5 CATALYSTS [J].

AGUDO, AL ;

BENITEZ, A ;

FIERRO, JLG ;

PALACIOS, JM ;

NEIRA, J ;

CID, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (03) :385-390

[2] CATALYTIC ACTIVITY AND SELECTIVITY IN THE CONVERSION OF METHANOL TO LIGHT OLEFINS [J].

BALKRISHNAN, I ;

RAO, BS ;

HEGDE, SG ;

KOTASTHANE, AN ;

KULKARNI, SB ;

RATNASWAMY, P .

JOURNAL OF MOLECULAR CATALYSIS, 1982, 17 (2-3) :261-270

[3]

BEZOUCHANOVA C, 1987, 6TH P INT S SOF 2, P216

[4]

BUCKLEY RI, 1985, COORDIN CHEM REV, V65, P167

[5]

CHUKIN GD, 1990, KINET KATAL, V31, P503

[6]

DAVIDOVA N, 1986, NEW DEV ZEOLITE SCI, P811

[7]

DENOUDEN CJJ, 1989, ZEOLITES FACTS FIGUR, V49, P1025

[8]

ECHIGOYA E, THEORY PRACTICE, V1, P332

[9]

EZZAMARTY A, 1989, 8TH REC RES REP INT, V49, P1025

[10] HYDRODESULFURIZATION OF THIOPHENE USING RHODIUM(III) ZEOLITES-13X AND ZEOLITES-ZSM-5 [J].

GIVENS, KE ;

DILLARD, JG .

JOURNAL OF CATALYSIS, 1984, 86 (01) :108-120

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