BINUCLEAR COMPLEXES OF NICKEL BRIDGED BY HYDROCARBON LIGANDS - ISOCYANIDE INSERTION CHEMISTRY AND AMIDE FORMATION BY INTRAMOLECULAR COUPLING OF ACYL AND IMIDOYL FUNCTIONALITIES

被引：22

作者：

CAMPORA, J

CARMONA, E

GUTIERREZ, E

PALMA, P

POVEDA, ML

RUIZ, C

机构：

[1] UNIV SEVILLA,CSIC,INST CIENCIA MAT,DEPT QUIM INORGAN,APDO 553,E-41071 SEVILLE,SPAIN

[2] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN

[3] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,E-28040 MADRID,SPAIN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ni(cod)(PMe3)2 and the o-, m-, and p-bromobenzyl bromides react, under appropriate conditions, to afford the binuclear complexes Ni2(mu(2)-eta(3),eta(1)-CH2C6H4)Br2(PMe3)3 (1a-c) or Ni2(mu(2)-eta(1),eta(1)-CH2C6H4)Br2(PMe3)4 (2b,c). The reaction of the ortho eta(3)-benzylic derivative 1a with isocyanides, CNR, has been investigated, and three different isomeric species have been identified for R = Bu(t). The CNC6H3-2,6-Me2 insertion product, 4, reacts with CO to form a Ni(II)-vinyl complex 7 derived from the N-aryl-1-isoquinolone 8, which can be freed by hydrolytic cleavage of the Ni-vinyl bond.

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页码：11 / 13

页数：3

相关论文

共 17 条

[1] ISOCYANIDE INSERTION REACTION OF ALKYL COMPLEXES OF IRON(II) [J].

BELLACHIOMA, G ;

CARDACI, G ;

ZANAZZI, P .

INORGANIC CHEMISTRY, 1987, 26 (01) :84-91

[2] COORDINATION PROPERTIES OF IMINO(2-PYRIDYL)METHYLPALLADIUM(II) COMPOUNDS - PREPARATION AND THERMAL REARRANGEMENT OF BINUCLEAR ADDUCTS WITH PALLADIUM(II) AND PLATINUM(II) CHLORIDES [J].

BERTANI, R ;

BERTON, A ;

DIBIANCA, F ;

CROCIANI, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 348 (03) :411-423

[3] NEW NICKEL ORTHO-METHYLBENZYL COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF NI(ETA-3-CH2C6H4-ORTHO-ME)CL(PME3) AND NI3(ETA-1-CH2C6H4-ORTHO-ME)4(PME3)2(MU-3-OH)2 [J].

CARMONA, E ;

MARIN, JM ;

PANEQUE, M ;

POVEDA, ML .

ORGANOMETALLICS, 1987, 6 (08) :1757-1765

[4] FORMATION OF ALKENYL KETONE COMPLEXES AND OF DIMERIC ALPHA,BETA-BUTENOLIDES BY SEQUENTIAL INSERTION OF PHENYLACETYLENE AND CARBON-MONOXIDE INTO NICKEL-ACYL BONDS - X-RAY STRUCTURES OF NI[C(PH)=C(H)(COCH2SIME3)]CL(PME3)2 AND NI[C(PH)(PME3)C(H)(COCH2CME2PH)]CL(PME3) [J].

CARMONA, E ;

GUTIERREZPUEBLA, E ;

MONGE, A ;

MARIN, JM ;

PANEQUE, M ;

POVEDA, ML .

ORGANOMETALLICS, 1989, 8 (04) :967-975

[5] ETA-1-ALKANEIMIDOYL AND ETA-2-ALKANEIMIDOYL COMPLEXES OF NICKEL - SYNTHESIS AND PROPERTIES [J].

CARMONA, E ;

PALMA, P ;

PANEQUE, M ;

POVEDA, ML .

ORGANOMETALLICS, 1990, 9 (03) :583-588

[6] MULTIPLE INSERTION REACTIONS OF CNBUT INTO NICKEL ALKYL BONDS [J].

CARMONA, E ;

MARIN, JM ;

PALMA, P ;

POVEDA, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 377 (01) :157-169

[7] SYNTHESIS AND X-RAY STRUCTURE OF THE NICKELABENZOCYCLOPENTENE COMPLEX (ME3P)2NI(CH2CME2-ORTHO-C6H4) - REACTIVITY TOWARD SIMPLE, UNSATURATED MOLECULES AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE CYCLIC CARBOXYLATE (ME3P)2NI(CH2CME2-ORTHO-C6H4C(O)O) [J].

CARMONA, E ;

GUTIERREZPUEBLA, E ;

MARIN, JM ;

MONGE, A ;

PANEQUE, M ;

POVEDA, ML ;

RUIZ, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :2883-2891

[8] SYNTHESIS AND CHARACTERIZATION OF SOME NEW ORGANOMETALLIC COMPLEXES OF NICKEL(II) CONTAINING TRIMETHYLPHOSPHINE [J].

CARMONA, E ;

PANEQUE, M ;

POVEDA, ML .

POLYHEDRON, 1989, 8 (03) :285-291

[9] SYNTHESIS AND REACTIVITY OF SATURATED HYDROCARBON-BRIDGED DINUCLEAR COMPLEXES [J].

CASEY, CP ;

AUDETT, JD .

CHEMICAL REVIEWS, 1986, 86 (02) :339-352

[10] INTRAMOLECULAR COUPLING OF ETA-2-IMINOACYL AND ETA-2-ACYL FUNCTIONS AT GROUP-4 AND GROUP-5 METAL CENTERS - STRUCTURE AND SPECTROSCOPIC PROPERTIES OF THE RESULTING ENAMIDOLATE AND ENEDIAMIDE COMPLEXES [J].

CHAMBERLAIN, LR ;

DURFEE, LD ;

FANWICK, PE ;

KOBRIGER, LM ;

LATESKY, SL ;

MCMULLEN, AK ;

STEFFEY, BD ;

ROTHWELL, IP ;

FOLTING, K ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (20) :6068-6076