SYNTHESIS AND CONFORMATIONAL-ANALYSIS OF COMPLEXES PREPARED BY REACTION OF ANIONS OF ALPHA-IMINOESTERS OR NITRILES WITH HALOBENZENETRICARBONYLCHROMIUM

被引：43

作者：

ROSEMUNCH, F ^{[1
]}

ANISS, K ^{[1
]}

ROSE, E ^{[1
]}

VAISSERMAN, J ^{[1
]}

机构：

[1] UNIV PARIS 06, CHIM METAUX TRANSIT LAB, URA 419, F-75252 PARIS 05, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 415卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80122-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of alpha-substituted arylimino esters or nitriles via an ipso nucleophilic aromatic substitution of carbanions of alpha-imino esters or nitriles on haloarenetricarbonylchromium complexes is reported: conformational studies of these complexes in solution have been studied and X-ray structures of three of these complexes indicated that the nitrile and ester groups are anti-periplanar to the tricarbonylchromium entity.

引用

页码：223 / 255

页数：33

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