STEREOSPECIFIC SYNTHESIS OF HYDROXYLATED STEROID SIDE-CHAINS - SYNTHESIS OF 25,28-DIHYDROXY-7,8-DIHYDROERGOSTEROL AND ITS C-24 EPIMER VIA [2,3] SIGMATROPIC REARRANGEMENT

被引：29

作者：

MIDLAND, MM

KWON, YC

机构：

来源：

TETRAHEDRON LETTERS | 1985年 / 26卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(01)80841-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：5017 / 5020

页数：4

共 22 条

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[7]

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[9] STEREOCONTROLLED SYNTHESIS OF 22-HYDROXY-23-ACETYLENIC STEROIDS, KEY INTERMEDIATES IN STEROID SIDE-CHAIN CONSTRUCTION - OBSERVATION OF A DIRECTIVE EFFECT BY AN ALPHA-CHIRAL SITE DURING ASYMMETRIC REDUCTION WITH B-3-PINANYL-9-BBN (ALPINE-BORANE) [J].

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[10] REDUCTION OF ALPHA,BETA-ACETYLENIC KETONES WITH B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE - HIGH ASYMMETRIC INDUCTION IN ALIPHATIC SYSTEMS [J].

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