SYNTHESIS OF AROMATIC POLYETHERS BY SCHOLL REACTION .10. SYNTHESIS AND CATION-RADICAL POLYMERIZATION OF 1,5-BIS(1-NAPHTHOXY)-3-OXAPENTANE

被引:6
作者
PERCEC, V
WANG, JH
YU, LS
机构
[1] Department of Macromolecular Science, Case Western Reserve University, Cleveland, 44106-2699, OH
关键词
D O I
10.1007/BF00300597
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper describes the synthesis and cation-radical polymerization of 1,5-bis(1-naphthoxy)-3-oxapentane. This monomer contains a flexible diethylene oxide unit between two 1-naphthalene rings. The FT-IR analysis of the resulted polymer indicates that it contains 1,4-disubstituted naphthalene structural units, i.e. 4,4'-disubstituted-1,1'-binaphthalene units. The polymer is crystalline with a melting point of 236-degrees-C.
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页码:503 / 510
页数:8
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