SYNTHESIS, STRUCTURE, AND NMR CHARACTERIZATION OF A NOVEL [3.3]-METACYCLOPHANE

被引：16

作者：

DOYLE, TJ

HASELTINE, J

机构：

[1] School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1994年 / 31卷 / 06期

关键词：

D O I：

10.1002/jhet.5570310620

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and crystal structure of metacyclophane 2 are reported. The nmr data relevant to conformational properties are also presented.

引用

页码：1417 / 1420

页数：4

共 16 条

[1]

FRIEBOLIN H, 1991, BASIC ONE 2 DIMENSIO, P269

[2]

Harris L., 1969, ORG PREP PROCED, V1, P147

[3]

KANAOKA Y, 1970, CHEM PHARM BULL, V18, P397

[4]

KEEHN PM, 1983, CYCLOPHANES 1

[5] CONFORMATIONAL-ANALYSIS .13. SYN AND ANTI [3.2]-METACYCLOPHANE, [3.3]-METACYCLOPHANE, [4.2]-METACYCLOPHANE, AND [4.3]-METACYCLOPHANE [J].

KROIS, D ;

LEHNER, H .

TETRAHEDRON, 1982, 38 (22) :3319-3324

[6] THE USE OF VARIABLE TEMPERATURE SE-77 NMR TO DETERMINE THE CONFORMATIONAL-CHANGES IN 2,11-DISELENA[3.3]METACYCLOPHANE [J].

MITCHELL, RH ;

WEERAWARNA, KS .

TETRAHEDRON LETTERS, 1988, 29 (44) :5587-5588

[7] THE SYNTHESIS AND REACTIONS OF 2,11-DISELENA[3,3]METACYCLOPHANES - AN INVESTIGATION OF THE SELENOXIDE ELIMINATION ROUTE TO METACYCLOPHANE-1,8-DIENES [J].

MITCHELL, RH .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (14) :1398-1406

[8] A CONFORMATIONAL STUDY OF [3.3]METACYCLOPHANES THROUGH VARIABLE-TEMPERATURE H-1-NMR AND OPTICAL-ROTATION [J].

SAKO, K ;

SHINMYOZU, T ;

TAKEMURA, H ;

SUENAGA, M ;

INAZU, T .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (24) :6536-6541

[9]

SASAKI H, 1988, CHEM PHARM BULL, V36, P1593

[10]

SASAKI H, 1987, CHEM PHARM BULL, V35, P4747

← 1 2 →