A SCHIFF-BASE DERIVED REDOX-RESPONSIVE RECEPTOR MOLECULE AND RELATED-COMPOUNDS WITH POTENTIAL AS NONLINEAR OPTICAL-MATERIALS

被引：45

作者：

BEER, PD

SIKANYIKA, H

机构：

[1] Department of Chemistry, University of Birmingham, Birmingham, B15 2TT

来源：

POLYHEDRON | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81299-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Schiff base redox-responsive receptor molecule (8) containing a ferrocene redox-active centre and a benzo-15-crown-5 metal cation binding unit is reported. The reversible redox couple of 8 shifts anodically on addition of Na+, K+ and Mg2+ guest cations. The synthesis and electrochemical properties of two related ferrocenyl Schiff base compounds (9 and 10) possessing electron-donor and -acceptor moieties which have potential as non-linear optical materials are also reported. © 1990.

引用

页码：1091 / 1094

页数：4

共 16 条

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[2] AMMONIUM REDOX-RESPONSIVE RECEPTORS CONTAINING 2 OR 3 FERROCENE REDOX-ACTIVE CENTERS ATTACHED TO DI-AZA AND TRI-AZA CROWN ETHER MACROCYCLES
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[4] REDOX RESPONSIVE CROWN ETHERS CONTAINING A DIRECT LINK BETWEEN THE FERROCENE REDOX-ACTIVE CENTER AND BENZO CROWN ETHER - CRYSTAL-STRUCTURE OF A FERROCENE BENZO-15-CROWN-5 SODIUM COMPLEX
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