A COMPLETE MODEL FOR THE CATALYTIC REDUCTION OF AN ALKYNE TO AN ALKYNE BY A TRINUCLEAR OSMIUM CLUSTER - THE X-RAY CRYSTAL-STRUCTURE OF CIS-[OS3(CO)11(CF3(H)C-C(H)CF3)]

被引：16

作者：

DAWOODI, Z

HENRICK, K

MAYS, MJ

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[2] POLYTECH N LONDON,DEPT CHEM,LONDON N7 8DB,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1982年 / 12期

关键词：

D O I：

10.1039/c39820000696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：696 / 698

页数：3

共 11 条

[1] REACTIONS INVOLVING HYDROGEN TRANSFER FROM TRIOSMIUM CLUSTERS TO AN ACTIVATED NITRILE [J].

ADAMS, RD ;

KATAHIRA, DA ;

YANG, LW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 219 (01) :85-101

[2] REVERSIBLE HYDROGENATION AND DEHYDROGENATION OF CLUSTER BOUND ACIMIDOYL AND ALKYLIDENIMIDO GROUPS - SYNTHESIS OF COMPLEXES CONTAINING TRIPLY BRIDGING NITRENE AND NITRILE LIGANDS [J].

ANDREWS, MA ;

KAESZ, HD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (24) :7255-7259

[3] STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES .1. CRYSTAL-STRUCTURES OF ISOMORPHOUS SPECIES H2OS3(CO)11 AND OS3(CO)12 - DIRECT INFORMATION ON ROLE OF AN EQUATORIAL MU-2-BRIDGING HYDRIDE LIGAND IN PERTURBING ARRANGEMENT OF CARBONYL LIGANDS IN A TRIANGULAR CLUSTER [J].

CHURCHILL, MR ;

DEBOER, BG .

INORGANIC CHEMISTRY, 1977, 16 (04) :878-884

[4] THE REACTION OF H2OS3(CO)10 WITH TRIFLUOROACETONITRILE AND THE X-RAY CRYSTAL-STRUCTURE OF HOS3(CO)9(MU3-ETAZ-HNCCF3) [J].

DAWOODI, Z ;

MAYS, MJ ;

RAITHBY, PR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 219 (01) :103-113

[5] FORMATION OF CLUSTER ALKENE COMPLEXES BY NUCLEOPHILIC-ATTACK ON A VINYL HYDRIDE CLUSTER - X-RAY CRYSTAL-STRUCTURES OF [(PH3P)2N][OS3(CO)10-[CF3(H)C-C(H)CF3]BR] AND [OS3(CO)10[CF3(H)C-C(H)CF3](PET3)] [J].

DAWOODI, Z ;

MAYS, MJ ;

RAITHBY, PR ;

HENRICK, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (14) :641-643

[6] REACTIONS OF ACETYLENE, METHYL-SUBSTITUTED AND PHENYL-SUBSTITUTED ACETYLENES, AND ETHYLENE WITH 1,1,1,1,2,2,2,3,3,3-DECACARBONYL-2,3-DI-MU-HYDRIDO-TRI-ANGULO-TRIOSMIUM [J].

DEEMING, AJ ;

HASSO, S ;

UNDERHILL, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (15) :1614-1620

[7] SYNTHESIS OF HYDRIDO-CARBONYL AND DEUTERIO-CARBONYL CLUSTER COMPLEXES OF RUTHENIUM, IRON-RUTHENIUM, AND OSMIUM FROM METAL-CARBONYLS AND HYDROGEN AT ATMOSPHERIC-PRESSURE [J].

KNOX, SAR ;

KOEPKE, JW ;

ANDREWS, MA ;

KAESZ, HD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (14) :3942-3947

[8] NEW MODE OF BONDING OF A VINYL LIGAND TO AN OSMIUM CLUSTER - X-RAY CRYSTAL-STRUCTURE OF [HOS3(CO)10(CF3CCHCF3)] [J].

LAING, M ;

SOMMERVILLE, P ;

DAWOOD, Z ;

MAYS, MJ ;

WHEATLEY, PJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (23) :1035-1036

[9]

LEWIS J, 1979, GAZZ CHIM ITAL, V109, P271

[10] ACTIVATION OF HYDROCARBONS BY UNSATURATED METAL CLUSTER COMPLEXES .2. SYNTHESIS, REACTIVITY, AND STRUCTURE OF MU-3-NETA-DIPHENYLACETYLENE)-DECACARBONYLTRIOSMIUM - METALLOCYCLOPENTADIENE FORMATION IN TRIOSMIUM SYSTEM [J].

TACHIKAWA, M ;

SHAPLEY, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (24) :7172-7174

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