THE DIRECT ELECTROCHEMICAL SYNTHESIS OF SOME TRANSITION-METAL CARBOXYLATES

被引：23

作者：

KUMAR, N

TUCK, DG

WATSON, KD

机构：

[1] Department of Chemistry and Biochemistry, University of Windsor, Windsor,ON,N9B3P4, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1987年 / 65卷 / 04期

关键词：

Copper compounds - Linoleic acid - Anodes - Carboxylation - Nickel compounds;

D O I：

10.1139/v87-125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transition metal carboxylates M(O2CR)n (M = Cr, R = C2H5, C6H5, n = 3; M = Mn, Fe, Ni, R = CH3, C2H5, C6H5, n-C7H15, n = 2, not all combinations) have been prepared by oxidising suitable metal anodes electrochemically in solutions of RCOOH in acetonitrile. With Co and Cu, a wide range of carboxylic acids (R = C2H5, C-C3H5, C-C5H9, C6H5, n-C4H9, n-C7H15, 2-ethylhexanoic, oleic, linoleic) has been used successfully to give M(O2CR)2. The advantages of the method are discussed. The preparation of Cu(O2CR)2 involves the prior formation of CuO2CR at the anode, followed by oxidation by the solvent.

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页码：740 / 743

页数：4

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