INVESTIGATION OF THE RESTRICTED DIFFUSION IN SPHERICAL CAVITIES OF POLYMERS BY PULSED-FIELD GRADIENT NUCLEAR-MAGNETIC-RESONANCE

被引：15

作者：

APPEL, M ^{[1
]}

FLEISCHER, G ^{[1
]}

KARGER, J ^{[1
]}

DIENG, AC ^{[1
]}

RIESS, G ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,CRPCSS,F-68093 MULHOUSE,FRANCE

来源：

MACROMOLECULES | 1995年 / 28卷 / 07期

关键词：

D O I：

10.1021/ma00111a030

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present results of pulsed field gradient nuclear magnetic resonance (PFG NMR) measurements of restricted diffusion of silicone oil (PDMS) dispersed in the continuous polystyrene phase of a two-phase system containing polystyrene (PS) and poly(dimethylsiloxane). These materials were synthesized by free-radical polymerization of styrene in a silicone oil/styrene emulsion in the presence of a polystyrene-poly(dimethylsiloxane) (PS-PDMS) block copolymer acting as an emulsifier. The diameters of the oil droplets could be derived from the echo attenuation plots of the PFG NMR experiments. They decrease with increasing temperature. The materials were observed to possess a thermally stable structure up to temperatures of 160 degrees C.

引用

页码：2345 / 2350

页数：6

共 14 条

[1] ANOMALOUS SEGMENT DIFFUSION IN POLYMER MELTS [J].