REDETERMINATION OF THE CRYSTAL-STRUCTURE OF HEXAAMMINECOBALT(II) CHLORIDE

被引：16

作者：

NEWMAN, JM ^{[1
]}

BINNS, M ^{[1
]}

HAMBLEY, TW ^{[1
]}

FREEMAN, HC ^{[1
]}

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 18期

关键词：

D O I：

10.1021/ic00018a021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of [Co(NH3)6]Cl2 has been redetermined at ambient and low temperatures. The compound forms cubic crystals, a = 10.1342 (7) angstrom at 294 K, with Z = 4. The structure has been refined in space group Fm3mBAR with allowance for the rotationally disordered ammine ligands (R = 0.025, R(w) = 0.021, 165 F's [> 5-sigma(F)]). The Co(II)-N bond length is 2.170 (2) angstrom. Diffraction measurements at 128 K yielded similar but less precise results [a = 10.012 (4) angstrom; Co(II)-N = 2.164 (4) angstrom].

引用

页码：3499 / 3502

页数：4

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