STUDIES IN AZIDE CHEMISTRY .14. THERMOLYSIS OF PERFLUORO-4-AZIDOPYRIDINE AND PERFLUORO-4-AZIDOTOLUENE IN THE PRESENCE OF PENTA-METHYLBENZENE AND HEXA-METHYLBENZENE

被引：8

作者：

BANKS, RE

MADANY, IM

机构：

[1] Chemistry Department, The University of Manchester Institute of Science and Technology, Manchester

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 47卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)82404-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of perfluoro-4-azidopyridine and perfluoro-4- azidotoluene in the presence of a large excess (10 molar) of pentamethylbenzene gave mainly (>60%) products expected from nitrene 'insertions' at the nuclear CH bond, i.e. ArFNHC6Me5 (ArF = 4-C5F4N, 4-C6F4CF3). Similar decomposition of perfluoro-4-azidotoluene in hexamethylbenzene gave a complex mixture containing perfluoro-p-toluidine. © 1990.

引用

页码：527 / 532

页数：6

共 5 条

[1] STUDIES IN AZIDE CHEMISTRY .13. INTERMOLECULAR INSERTION OF AZIDE-DERIVED POLYFLUORINATED ARYL-NITRENE AND HETEROARYL-NITRENE INTO RING C-H BONDS OF 1,3,5-TRIMETHYL-BENZENE AND 1,3,5-TRIMETHOXY-BENZENE
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[3] STUDIES IN AZIDE CHEMISTRY .6. SOME REACTIONS OF PERFLUOROAZIDOBENZENE AND PERFLUORO-4-AZIDOTOLUENE
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[4] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .18. RATES OF CHLORINATION OF BENZENE, TOLUENE AND THE XYLENES - PARTIAL RATE FACTORS FOR THE CHLORINATION REACTION
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[5] RELATIVE RATES OF BROMINATION OF BENZENE AND THE METHYLBENZENES - PARTIAL RATE FACTORS FOR THE BROMINATION REACTION
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