C-13 AND PT-195 NMR OF PARA-SUBSTITUTED N,N-DIALKYL-N'-BENZOYLTHIOUREAS AND THEIR CIS-[ML2] COMPLEXES, M = PD(II) AND PT(II)

被引：15

作者：

KOCH, KR

MATOETOE, MC

机构：

[1] Department of Chemistry, University of Cape Town, Cape Town, 7700, Private Bag, Rondebosch

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1991年 / 29卷 / 11期

关键词：

C-13; NMR; N; N-DI-N-BUTYL-N'-BENZOYLTHIOUREAS; N-DIETHYL-N'-BENZOYLTHIOUREAS; PT-195; PLATINUM(II) AND PALLADIUM(II) COMPLEXES;

D O I：

10.1002/mrc.1260291114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of neutral cis‐[ML2] complexes, where M = Pd(II) and Pt(II) and L = para‐substituted N,N‐dialkyl‐N′‐benzoyl‐thio‐urea anion, were examined by means of 13C and 195Pt NMR. Unambiguous assignment of the thiocarbonyl carbon atom in these complexes was achieved with 13C isotopic enrichment and the resolved nJ(195Pt, 13C) coupling satellites. Copyright © 1991 John Wiley & Sons Ltd.

引用

页码：1158 / 1160

页数：3

共 7 条

[1] D-NMR STUDIES OF HINDERED ROTATION ON N-C(X) BOND INCREMENT .8. METAL-COMPLEXES OF 1,1-DIETHYL-3-BENZOYLTHIOUREA AND SELENOUREA [J].