GAS-CHROMATOGRAPHIC RETENTION BEHAVIOR OF ALKYLATED PHENANTHRENES ON A SMECTIC LIQUID-CRYSTALLINE PHASE - APPLICATION TO ORGANIC GEOCHEMISTRY

被引：27

作者：

BUDZINSKI, H

RADKE, M

GARRIGUES, P

WISE, SA

BELLOCQ, J

WILLSCH, H

机构：

[1] UNIV BORDEAUX 1, CNRS, URA 348, F-33405 TALENCE, FRANCE

[2] FORSCHUNGSZENTRUM JULICH, RES CTR, INST PETR & ORGAN GEOCHEM, W-5170 JULICH 1, GERMANY

[3] NATL INST STAND & TECHNOL, DIV ORGAN ANALYT CHEM, GAITHERSBURG, MD 20899 USA

来源：

JOURNAL OF CHROMATOGRAPHY | 1992年 / 627卷 / 1-2期

关键词：

D O I：

10.1016/0021-9673(92)87202-J

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The retention indices for the 30 C2 phenanthrenes and 33 trimethylphenanthrenes were determined by gas chromatography on a smectic liquid crystalline phase. The retention behaviour of these alkylated phenanthrenes was related to molecular shape considerations: length-to-breadth ratio, dihedral angle and substitution pattern. In addition, the influence on the retention behaviour of the arc-like shape of the phenanthrene molecule was investigated. Based on these results, 12 C2 phenanthrenes and 25 trimethylphenanthrenes were identified in natural samples, such as crude oils and rock extracts.

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页码：227 / 239

页数：13

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