STEREOSELECTIVE SYNTHESIS OF TAXOL DERIVATIVES

被引：25

作者：

BLECHERT, S

MULLER, R

BEITZEL, M

机构：

[1] Technische Universität Berlin, D-1000 Berlin 12

来源：

TETRAHEDRON | 1992年 / 48卷 / 34期

关键词：

D O I：

10.1016/S0040-4020(01)91207-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoselective synthesis of the tricyclic taxane system with three oxygen centers in ring B is achieved by a photocycloaddition followed by elimination yielding a cyclobutene and oxidative ring expansion. By this strategy a variety of functionalized A,B-ring systems can also be established.

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页码：6953 / 6964

页数：12

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