STRUCTURAL-CHANGE IN LITHIUM INTERCALATION OF LAYERED PEROVSKITE LILANB2O7

被引：25

作者：

SATO, M

JIN, T

UEDA, H

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 01期

关键词：

D O I：

10.1246/cl.1994.161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical lithium intercalation of a layered perovskite LiLaNb2O7 compound has been performed by using n-butyllithium. The content of inserted lithium ions was found to be ca. 1 mol per unit formula. The crystal structure of the intercalated compound was determined by the powder X-ray diffraction pattern. An unusual contraction of the cell volume inherent in the intercalation reaction was observed.

引用

收藏

页码：161 / 164

页数：4

相关论文

共 14 条

[1] THE NEW PHASE FAMILIES MIM2(II)NB3010 WITH PEROVSKITE SHEETS [J].

DION, M ;

GANNE, M ;

TOURNOUX, M .

MATERIALS RESEARCH BULLETIN, 1981, 16 (11) :1429-1435

[2]

GONDRAND M, 1987, REV CHIM MINER, V24, P33

[3] A(I)LANB2O7 - A NEW SERIES OF LAYERED PEROVSKITES EXHIBITING ION-EXCHANGE AND INTERCALATION BEHAVIOR [J].

GOPALAKRISHNAN, J ;

BHAT, V ;

RAVEAU, B .

MATERIALS RESEARCH BULLETIN, 1987, 22 (03) :413-417

[4] A2LN2TI3O10 (A = K OR RB, LN = LA OR RARE-EARTH) - A NEW SERIES OF LAYERED PEROVSKITES EXHIBITING ION-EXCHANGE [J].

GOPALAKRISHNAN, J ;

BHAT, V .

INORGANIC CHEMISTRY, 1987, 26 (26) :4299-4301

[5] LITHIUM INSERTION INTO FE3O4 [J].

ISLAM, MS ;

CATLOW, CRA .

JOURNAL OF SOLID STATE CHEMISTRY, 1988, 77 (01) :180-189

[6]

IZUMI F, 1978, NIPPON KESSHOU GAKKA, V27, P23

[7] ION-EXCHANGE REACTIONS OF THE LAYERED SOLID ACID HCA2NB3O10 WITH ALKALI-METAL CATIONS [J].

JACOBSON, AJ ;

LEWANDOWSKI, JT ;

JOHNSON, JW .

MATERIALS RESEARCH BULLETIN, 1990, 25 (05) :679-686

[8] INTERLAYER CHEMISTRY BETWEEN THICK TRANSITION-METAL OXIDE LAYERS - SYNTHESIS AND INTERCALATION REACTIONS OF K[CA2NAN-3NBNO3N+1] (3 LESS-THAN-OR-EQUAL-TO N LESS-THAN-OR-EQUAL-TO 7) [J].

JACOBSON, AJ ;

JOHNSON, JW ;

LEWANDOWSKI, JT .

INORGANIC CHEMISTRY, 1985, 24 (23) :3727-3729

[9] SYNTHESIS AND INTERCALATION CHEMISTRY OF K(CA-2(CA,SR)N-3NB3TIN-3O3N+1) (N = 4, 5) [J].

RAM, RAM ;

CLEARFIELD, A .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 94 (01) :45-51

[10]

RUDDLESDEN SN, 1958, ACTA CRYSTALLOGR, V11, P45