ISOLATION AND CHARACTERIZATION OF IRON(II) COMPLEXES WITH DINITROGEN, AND OF OTHER DERIVATIVES, ESPECIALLY FROM PHENYLACETYLENE

被引:34
作者
HUGHES, DL [1 ]
LEIGH, GJ [1 ]
JIMENEZTENORIO, M [1 ]
ROWLEY, AT [1 ]
机构
[1] UNIV SUSSEX, INST PLANT SCI RES, AFRC, NITROGEN FIXAT LAB, BRIGHTON BN1 9RQ, E SUSSEX, ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 01期
关键词
D O I
10.1039/dt9930000075
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex [FeCl2(dmpe)2] (dmpe = Me2PCH2CH2PMe2) dissolves in alcohols under dinitrogen to yield the dinitrogen complex [FeCl(N2)(dmpe)2]+. Reactions of [FeCl2(dmpe)2] with PhC-CH yield the interconvertible acetylide and vinylidene complexes [FeCl(C=CPh)(dmpe)2] and [FeCl(C=CHPh)-(dmpe)2]+, the structures of which have been determined- Related complexes of Et2PCH2CH2PEt2 have been prepared, as well as similar complexes containing ligands such as MeNC, CO, etc.
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收藏
页码:75 / 82
页数:8
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