FLUORESCENCE PROBES AS A TOOL FOR STUDYING MICROENVIRONMENT OF SUPPORTED SPECIES .1. SOLVATOCHROMIC SHIFT IN RELATION WITH SITE ACCESSIBILITY

被引:10
作者
CARLIER, E
REVILLON, A
GUYOT, A
CHAUVET, JP
机构
[1] CNRS,MAT ORGAN LAB,LYON SOLAISE,BP 24,F-69390 VERNAISON,FRANCE
[2] ECOLE NORMALE SUPER LYON,STEREOCHIM & INTERACT MOLEC LAB,UMR 117,F-69364 LYON 07,FRANCE
关键词
D O I
10.1016/0014-3057(93)90333-B
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Comparison of solvatochromic shift of fluorescent probes attached to various supports with values obtained for the free probes in the same set of solvents is a way to examine the micro-environment of the fluorophore. Interpretation of emission spectra of dansyl probes bonded to native or neutralized silica. either directly or via polar or non-polar polymers, allows determination of the influences of organic and inorganic parts in bi-supported functional sites.
引用
收藏
页码:819 / 823
页数:5
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