HETEROGENEOUS PHOTOCATALYSIS - AN EMERGING TECHNOLOGY FOR WATER-TREATMENT

被引:301
作者
HERRMANN, JM
GUILLARD, C
PICHAT, P
机构
[1] URA au CNRS PHOTOCATALYSE, CATALYSE, ENVIRONNEMENT Ecole Centrale de Lyon, 69131 Ecully Cédex
关键词
D O I
10.1016/0920-5861(93)80003-J
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Heterogeneous photocatalysis is capable of destroying many organic micropollutants in aqueous medium. The principle of the method and a brief survey of the relevant literature are presented. On the basis of studies on the degradation of various substituted aromatics in UV-irradiated TiO2 aqueous suspensions carried out principally in our laboratory, we indicate the kinetic characteristics of the method, the nature of the intermediates and the degradation pathways, as well as the influence of pH or common ions and other parameters. The photocatalytic recovery of noble metals and the detoxification of water containing certain inorganic ions are also described. The advantages and disadvantages of the photocatalytic method, which begins to be commercialized, are briefly discussed.
引用
收藏
页码:7 / 20
页数:14
相关论文
共 98 条
[11]   SUNLIGHT PHOTODEGRADATION OF 2,4,5-TRICHLOROPHENOXY-ACETIC ACID AND 2,4,5,TRICHLOROPHENOL ON TIO2 - IDENTIFICATION OF INTERMEDIATES AND DEGRADATION PATHWAY [J].
BARBENI, M ;
MORELLO, M ;
PRAMAURO, E ;
PELIZZETTI, E ;
VINCENTI, M ;
BORGARELLO, E ;
SERPONE, N .
CHEMOSPHERE, 1987, 16 (06) :1165-1179
[12]  
BIDEAU M, 1991, J PHOTOCH PHOTOBIO A, V6, P269
[13]  
BIDEAU M, 1989, J PHOTOCHEM, V14, P29
[14]  
BORELLO R, 1989, ENVIRON TOXICOL CHEM, V8, P997, DOI [10.1897/1552-8618(1989)8[997:PDODMI]2.0.CO
[15]  
2, 10.1002/etc.5620081105]
[16]   LIGHT-INDUCED REDUCTION OF RHODIUM(III) AND PALLADIUM(II) ON TITANIUM-DIOXIDE DISPERSIONS AND THE SELECTIVE PHOTOCHEMICAL SEPARATION AND RECOVERY OF GOLD(III), PLATINUM(IV), AND RHODIUM(III) IN CHLORIDE MEDIA [J].
BORGARELLO, E ;
SERPONE, N ;
EMO, G ;
HARRIS, R ;
PELIZZETTI, E ;
MINERO, C .
INORGANIC CHEMISTRY, 1986, 25 (25) :4499-4503
[17]  
BORGARELLO E, 1985, NEW J CHEM, V9, P743
[18]  
BRAUN AM, 1991, PHOTOCHEMICAL CONVERSION AND STORAGE OF SOLAR ENERGY, P551
[19]   PHOTOCATALYTIC HYDROXYLATION OF BENZOIC-ACID IN AQUEOUS TITANIUM-DIOXIDE SUSPENSION [J].
BREZOVA, V ;
CEPPAN, M ;
BRANDSTETEROVA, E ;
BREZA, M ;
LAPCIK, L .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 59 (03) :385-391
[20]  
CASADO J, 1990, PHYSICOCHEMICAL BEHA, P28