AQUEOUS SOLUBILITIES OF CHLOROCATECHOLS, CHLOROVANILLINS, CHLOROSYRINGOLS, AND CHLOROSYRINGALDEYDES AT 25-DEGREES-C

被引：9

作者：

VARHANICKOVA, D ^{[1
]}

LEE, SC ^{[1
]}

SHIU, WY ^{[1
]}

MACKAY, D ^{[1
]}

机构：

[1] UNIV TORONTO, CTR PULP & PAPER, DEPT CHEM ENGN & APPL CHEM, TORONTO, ON M5S 1A4, CANADA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1995年 / 40卷 / 03期

关键词：

D O I：

10.1021/je00019a018

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The aqueous solubilities of 13 chlorinated derivatives of phenol (3,5-dichlorocatechol, 4,5-dichlorocatechol, 3,4,5-trichlorocatechol, tetrachlorocatechol, vanillin, 5-chlorovanillin, 6-chlorovanillin, 5,6-dichlorovanillin, 3-chlorosyringol, 3,5-dichlorosyringol, trichlorosyringol, 2-chlorosyringaldehyde, and 2,6-dichlorosyringaldehyde) were determined at 25 degrees C, by using a conventional shake-flask, batch contacting method with analysis by high-pressure liquid chromatography with UV detection. The liquid or supercooled liquid solubilities are satisfactorily correlated with the solute's LeBas molar volume, yielding structure-property relationships that may be useful for predictive purposes.

引用

页码：620 / 622

页数：3

共 11 条

[1]

[Anonymous], 1987, PROPERTIES GASES LIQ

[2]

DEAN JA, 1985, LANGES HDB CHEM

[3]

FIESER LF, 1959, INTRO ORGANIC CHEM

[4] AQUEOUS SOLUBILITIES OF CHLORINATED PHENOLS AT 25-DEGREES-C [J].

MA, KC ;

SHIU, WY ;

MACKAY, D .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (03) :364-366

[5]

Mackay D, 1992, ILLUSTRATED HDB PHYS, VI

[6]

Perrin D. D., 1981, PKA PREDICTION ORGAN

[7] AQUEOUS SOLUBILITY OF CHLOROGUAIACOLS [J].

TAM, D ;

VARHANICKOVA, D ;

SHIU, WY ;

MACKAY, D .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (01) :83-86

[8] The melting heat, specific cohesion and molecular size in the melting temperature [J].

Walden, P .

ZEITSCHRIFT FUR ELEKTROCHEMIE UND ANGEWANDTE PHYSIKALISCHE CHEMIE, 1908, 14 :713-724

[9] ESTIMATION OF ENTROPIES OF FUSION OF ORGANIC-COMPOUNDS [J].

YALKOWSKY, SH .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1979, 18 (02) :108-111

[10]

1991, CANADIAN ENV PROTECT

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