STRUCTURE AND REACTIONS OF BENZO-4-DIPHENYLPHOSPHINO-2-PHENYL-1,3,2-DIOXABORINANE

被引：6

作者：

NIKONOV, GN

BALUEVA, AS

KARASIK, AA

LITVINOV, IA

PROKHOROVA, SR

KATAEVA, ON

机构：

[1] Russian Academy of Sciences, Kazan Scientific Centre, A. E. Arbuzov Institute of Organic and Physical Chemistry

来源：

HETEROATOM CHEMISTRY | 1994年 / 5卷 / 01期

关键词：

D O I：

10.1002/hc.520050109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of 5,6-benzo-4-diphenylphosphino-2-phenyl-1,3,2-dioxaborinane 1 indicates the occurrence of an interaction between the pi-systems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group of the diphenylphosphino group. Complexes of compound 1 with PtCl2, PdCl2, and Cul were synthesized. Compound 1 and its complexes are readily hydrolyzed in solution to give diphenylphosphine and its corresponding complexes (NMR).

引用

页码：43 / 49

页数：7

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