BINUCLEAR TUNGSTEN RHENIUM ALKYL ACYL AND ALKYL CARBENE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF (CO)4W(MU-PPH2)2RE(CO)3CH3

被引：34

作者：

MERCER, WC

GEOFFROY, GL

RHEINGOLD, AL

机构：

[1] PENN STATE UNIV, DEPT CHEM, UNIVERSITY PK, PA 16802 USA

[2] UNIV DELAWARE, DEPT CHEM, NEWARK, DE 19716 USA

来源：

ORGANOMETALLICS | 1985年 / 4卷 / 08期

关键词：

D O I：

10.1021/om00127a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1418 / 1425

页数：8

共 21 条

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[10] STEPWISE TRANSFORMATION OF A TERMINALLY BOUND ALKYLIDYNE LIGAND TO A BRIDGING ACYL GROUP AT A BIMETAL CENTER VIA AN ASYMMETRICALLY BRIDGING ALKYL - X-RAY CRYSTAL-STRUCTURES OF [N(PPH3)2][REW(MU-CHR)(CO)9] (R = C6H4ME-4), [REW(MU-CH2R)(MU-ME2PCH2PME2)(CO)7], AND [REW(MU-OCCH2R)(MU-PH2PCH2PPH2)(CO)6(P(OME)3)]NG [J].

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