THE STAUDINGER REACTION OF ORTHO-AZIDOBENZALDEHYDE WITH TRIPHENYLPHOSPHINE REVISITED - INFLUENCE OF THE TEMPERATURE ON THE NATURE OF THE REACTION-PRODUCTS

被引：27

作者：

MOLINA, P

ARQUES, A

CARTAGENA, I

OBON, R

机构：

[1] Departamento de Química Orgànica, Facultad de Ciencias, Universidad de Murcia, 30070 Murcia, Campus de Espinardo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)74371-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of o-azidobenzaldehyde 1 with TPP at 0-degrees-C leads to the expected iminophosphorane 2 and the indazole derivative 3 while at -20-degrees-C the phosphazide 4 was the only reaction product. The close related compounds 2 and 4 shows striking differences in reactivity towards primary amines.

引用

页码：2521 / 2524

页数：4